Night-time radical chemistry during NAMBLEX

نویسندگان

  • R. Sommariva
  • M. J. Pilling
  • W. J. Bloss
  • D. E. Heard
  • J. D. Lee
  • Z. L. Fleming
  • P. S. Monks
  • J. M. C. Plane
  • A. Saiz-Lopez
  • S. M. Ball
  • M. Bitter
  • R. L. Jones
  • N. Brough
  • S. A. Penkett
  • J. R. Hopkins
  • A. C. Lewis
چکیده

R. Sommariva, M. J. Pilling, W. J. Bloss, D. E. Heard, J. D. Lee, Z. L. Fleming, P. S. Monks, J. M. C. Plane, A. Saiz-Lopez, S. M. Ball, M. Bitter, R. L. Jones, N. Brough, S. A. Penkett, J. R. Hopkins, A. C. Lewis, and K. A. Read School of Chemistry, University of Leeds, Leeds, UK Department of Chemistry, University of Leicester, Leicester, UK School of Environmental Sciences, University of East Anglia, Norwich, UK University Chemical Laboratory, University of Cambridge, Cambridge, UK Department of Chemistry, University of York, York, UK Now at Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA Now at Department of Chemistry, University of York, York, UK Now at School of Chemistry, University of Leeds, Leeds, UK Now at NASA Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USA Now at Department of Chemistry, University of Leicester, Leicester, UK

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Night-time radical chemistry during the NAMBLEX campaign

Night-time chemistry in the Marine Boundary Layer has been modelled using a number of observationally constrained zero-dimensional box-models. The models were based upon the Master Chemical Mechanism (MCM) and the measurements were taken during the North Atlantic Marine Boundary Layer Experiment (NAMBLEX) campaign at Mace Head, Ireland in July–September 2002. The model could reproduce, within t...

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OH and HO2 during NAMBLEX

Concentrations of OH and HO2 radicals during NAMBLEX: measurements and steady state analysis S. C. Smith, J. D. Lee, W. J. Bloss, G. P. Johnson, and D. E. Heard School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK Received: 19 September 2005 – Accepted: 1 October 2005 – Published: 28 November 2005 Correspondence...

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OH and HO2 chemistry during NAMBLEX: roles of oxygenates, halogen oxides and heterogeneous uptake

Several zero-dimensional box-models with different levels of chemical complexity, based on the Master Chemical Mechanism (MCM), have been used to study the chemistry of OH and HO2 in a coastal environment in the Northern Hemisphere. The models were constrained to and compared with measurements made during the NAMBLEX campaign (Mace Head, Ireland) in summer 2002. The base models, which were cons...

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OH and HO2 chemistry during NAMBLEX

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Concentrations of OH and HO2 radicals during NAMBLEX: measurements and steady state analysis

OH and HO2 concentrations were measured simultaneously at the Mace Head Atmospheric Research Station in the summer of 2002 during the NAMBLEX (North Atlantic Marine Boundary Layer EXperiment) field campaign. OH was measured by laser-induced fluorescence employing the FAGE (Fluorescence Assay by Gas Expansion) technique, with a mean daytime detection limit of 2.7×105 molecule cm−3 (5 min acquisi...

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تاریخ انتشار 2006